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I tried Lightroom and it's great. But I got used to PS so I'll stick with it

The built-in Windows 10 photo viewer also offers some basic editing pictures but I think it can't read raw files so they don't come up on the PC. Can photoshop display Raw photos exactly as you see them in the camera? Does it make sense to switch to Raw shooting mode only when it's dark or when you have to use high ISO? I ask because I usually want to save space but occasionally aim for a better than average quality photo. I'll be out experimenting tomorrow. Thanks.